Semiconductor devices and methods of manufacturing the same

ABSTRACT

A semiconductor device includes a substrate including first and second region, a bit line structure on the first region, key structures on the second region, each key structure having an upper surface substantially coplanar with an upper surface of the bit line structure, a first trench disposed between two adjacent key structures spaced apart from each other in a first direction, a filling pattern in a lower portion of the first trench, the filling pattern having a flat upper surface and including a first conductive material, and a first conductive structure on the flat upper surface of the filling pattern, an upper sidewall of the first trench, and the upper surface of each of the plurality of key structures, the first conductive structure including a second conductive material.

CROSS-REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. application Ser. No.16/903,040 filed on Jun. 16, 2020 which claims priority under 35 U.S.C.§ 119 to Korean Patent Application No. 10-2019-0136634 filed on Oct. 30,2019 in the Korean Intellectual Property Office, the disclosure of eachof which is hereby incorporated by reference in its entirety.

TECHNICAL FIELD

Example embodiments of the present disclosure relate to semiconductordevices and methods of manufacturing the same, and more specifically, todynamic random access memory (DRAM) devices and methods of manufacturingthe same.

DISCUSSION OF RELATED ART

Structures in a chip region of a DRAM device may be formed by using anoverlay key on a scribe lane region of a semiconductor wafer. Theoverlay key may include key structures and a trench therebetween. Ifresidue generated during processes for forming structures on a chipregion of the semiconductor wafer is stuck in the trench not to beremoved in a cleansing process, the residue may damage other structuresduring subsequent processes.

SUMMARY

Example embodiments provide a semiconductor device having improvedelectrical characteristics.

Example embodiments provide a method of manufacturing a semiconductordevice having improved electrical characteristics.

According to an exemplary embodiment of the present invention, asemiconductor device includes a substrate including a first region and asecond region surrounding the first region, a bit line structure on thefirst region of the substrate, a plurality of key structures on thesecond region of the substrate, each of the key structures having anupper surface substantially coplanar with an upper surface of the bitline structure, a first trench disposed between two adjacent keystructures of the plurality of key structures, wherein the two adjacentkey structures are spaced apart from each other in a first directionsubstantially parallel to an upper surface of the substrate, a fillingpattern in a lower portion of the first trench, the filling patternhaving a flat upper surface and including a first conductive material,and a first conductive structure on the flat upper surface of thefilling pattern, an upper sidewall of the first trench, and the uppersurface of each of the plurality of key structures, the first conductivestructure including a second conductive material.

According to an exemplary embodiment of the present invention, asemiconductor device includes a substrate including a first region and asecond region surrounding the first region, a plurality of keystructures on the second region of the substrate, each of the pluralityof key structures including an insulation pattern, a first conductivestructure, a barrier pattern, a metal pattern and a capping patternsequentially stacked, a first trench disposed between two adjacent keystructures of the plurality of key structures that are spaced apart fromeach other in a first direction substantially parallel to an uppersurface of the substrate, a filling pattern in a lower portion of thefirst trench, the filling pattern having a flat upper surface andincluding a conductive material, and a second conductive structure onthe flat upper surface of the filling pattern, an upper sidewall of thefirst trench, and upper surfaces of the plurality of key structures.

According to an exemplary embodiment of the present inventive concept, asemiconductor device includes a substrate including a first region and asecond region surrounding the first region, the substrate includingfirst and second active patterns on the first region and the secondregion, respectively, the first and second active patterns being definedby an isolation pattern on the substrate, a first gate structure in anupper portion of the first active pattern, a plurality of bit linestructures on the first region of the substrate, a first contact plugstructure on the first active pattern and between two adjacent bit linestructures of the plurality of bit line structures, a capacitor on thefirst contact plug structure, a plurality of key structures on thesecond region of the substrate, each of the plurality of key structureshaving an upper surface substantially coplanar with an upper surface ofeach of the plurality of bit line structures, a trench disposed betweentwo adjacent key structures of the plurality of key structures that arespaced apart from each other, a filling pattern in a lower portion ofthe trench, the filling pattern having a flat upper surface andincluding a conductive material, and a first conductive structure on theflat upper surface of the filling pattern, an upper sidewall of thetrench, and the upper surface of each of the plurality of keystructures.

According to an exemplary embodiment of the present invention, asemiconductor device includes a substrate including a first region and asecond region surrounding the first region, a bit line structure on thefirst region of the substrate, a key structure on the second region ofthe substrate, the key structure having the same stacked structure asthe bit line structure, and a filling pattern and a first conductivestructure sequentially stacked adjacent to the key structure. Thefilling pattern has a flat upper surface and includes a conductivematerial. The first conductive structure is formed on the flat uppersurface of the filling pattern and an upper surface of the keystructure.

According to an exemplary embodiment of the present invention, a methodof manufacturing a semiconductor device includes forming a plurality offirst structures and a plurality of key structures on a first region anda second region, respectively, of a substrate, the second regionsurrounding the first region, the plurality of first structures beingspaced apart from each other by a first trench, and the plurality of keystructures being spaced apart from each other by a second trench,forming a first filling layer on the plurality of first structures andthe plurality of key structures to fill the first trench and the secondtrench, wherein the first filling layer has a first height differenceamong portions of the first filling layer, performing a melting processon the first filling layer to form a second filling layer, wherein thesecond filling layer has a second height difference among portions ofthe second filling layer, the second height difference being smallerthan the first height difference, planarizing the second filling layeruntil upper surfaces of the plurality of first structures and theplurality of key structures are exposed to form first and second fillingpatterns between the plurality of first structures and between theplurality of key structures respectively, removing upper portions of thefirst and second filling patterns, forming a conductive layer on thefirst and second filling patterns, the plurality of first structures,and the plurality of key structures, planarizing the conductive layer toform a planarized conductive layer, and patterning a first portion ofthe planarized conductive layer on the first region of the substrateusing a second portion of the planarized conductive layer on the secondfilling pattern as an overlay key. The second portion of the planarizedconductive layer includes an upper surface defining a third trench asthe overlay key.

According to an exemplary embodiment of the present invention, a methodof manufacturing a semiconductor device includes forming a plurality offirst structures and a plurality of second structures on a first regionand a second region, respectively, of a substrate, the second regionsurrounding the first region, the plurality of first structures beingspaced apart from each other by a first trench having a first width, andthe plurality of second structures being spaced apart from each other bya second trench having a second width greater than the first width,forming a first filling layer in the first trench and the second trench,portions of the first filling layer on the second region of thesubstrate having a height difference from each other, performing amelting process on the first filling layer to form a second fillinglayer, wherein a height difference among portions of the second fillinglayer is smaller than the height difference among the portions of thefirst filling layer, planarizing the second filling layer until uppersurfaces of the plurality of first structures and upper surfaces of theplurality of second structures are exposed to form a plurality of firstfilling patterns between the plurality of first structures and aplurality of second filling patterns between the plurality of secondstructures respectively, removing upper portions of the plurality offirst filling patterns and upper portions of the plurality of secondfilling patterns, and forming a conductive layer with a third trench onthe plurality of first filling patterns and the plurality of secondfilling patterns.

According to an exemplary embodiment of the present invention, a methodof manufacturing a semiconductor device includes forming a plurality ofbit line structures and a plurality of key structures on a cell regionand a second region, respectively, of a substrate, the substrateincluding a first region having the cell region and a peripheral circuitregion at least partially surrounding the cell region, the second regionsurrounding the first region, the plurality of bit line structures beingspaced apart from each other by a first trench, and the plurality of keystructures being spaced apart from each other by a second trench,forming a first conductive layer on the plurality of bit line structuresand the plurality of key structures to fill the first trench and thesecond trench, performing a melting process on the first conductivelayer to form a second conductive layer, wherein a height differenceamong portions of the second conductive layer is smaller than a heightdifference among portions of the first conductive layer, planarizing thesecond conductive layer until upper surfaces of the plurality of bitline structures and upper surfaces of the plurality of key structuresare exposed to form a lower contact plug between two adjacent bit linestructures of the plurality of bit line structures and a filling patternbetween two key structures of the plurality of key structures, removingan upper portion of the lower contact plug and an upper portion of thefilling pattern, forming a second conductive layer with a third trenchon the lower contact plug, the filling pattern, the plurality of bitline structures, and the plurality of key structures, planarizing thesecond conductive layer to form a planarized second conductive layerwith a fourth trench, and patterning portions of the planarized secondconductive layer on the cell region and the peripheral circuit region,respectively, of the substrate to form an upper contact plug and awiring, respectively. Patterning of the portions of the planarizedsecond conductive layer includes aligning a mask for the patterning ofthe portion of the planarized second conductive layer using the fourthtrench of the planarized second conductive layer as an overlay key.

In a method of manufacturing a semiconductor device in accordance withexample embodiments, slurry particles remaining in a trench serving asan overlay key after a CMP process may not damage other structures. Theoverlay key may have an almost vertical sidewall, and thus wirings maybe formed to have a desired shape and layout using the overlay key.Accordingly, the semiconductor device may have improved electricalcharacteristics.

BRIEF DESCRIPTION OF THE DRAWINGS

FIGS. 1 to 38 are plan views and cross-sectional views illustrating amethod of manufacturing a semiconductor device according to exampleembodiments.

FIGS. 39 to 42 are cross-sectional views illustrating a method ofmanufacturing a semiconductor device according to a comparativeembodiment.

DETAILED DESCRIPTION

The above and other aspects and features of the semiconductor devicesand the methods of manufacturing the same in accordance with exampleembodiments will become readily understood from detail descriptions thatfollow, with reference to the accompanying drawings. It will beunderstood that, although the terms “first,” “second,” and/or “third”may be used herein to describe various elements, components, regions,layers and/or sections, these elements, components, regions, layersand/or sections should not be limited by these terms. These terms areonly used to distinguish one element, component, region, layer orsection from another region, layer or section. Thus, a first element,component, region, layer or section discussed below could be termed asecond or third element, component, region, layer or section withoutdeparting from the teachings of inventive concepts.

FIGS. 1 to 38 are plan views and cross-sectional views illustrating amethod of manufacturing a semiconductor device according to exampleembodiments. Specifically, FIGS. 1-3, 6, 11, 22 and 35 are the planviews, and FIGS. 4-5, 7-10, 12-21, 23-34 and 36-38 are thecross-sectional views.

FIG. 2 is an enlarged cross-sectional view of a region X of FIG. 1,FIGS. 3, 6, 11, 22 and 35 are enlarged cross-sectional views of regionsY and Z of FIG. 2, FIGS. 4, 7, 9, 12, 14, 16, 18, 20, 23-24, 26, 28, 31,33 and 36 include cross-sections taken along lines A-A′ and B-B′ ofregion Y of corresponding plan views, and FIGS. 5, 8, 10, 13, 15, 17,19, 21, 25, 27, 29-30, 32, 34 and 37-38 include cross-sections takenalong lines C-C′ and D-D′ of regions Z and W of corresponding planviews.

Hereinafter in the specifications (not necessarily in the claims), twodirections substantially parallel to an upper surface of a substrate 100and substantially perpendicular to each other may be defined as firstand second directions, respectively, and a direction substantiallyparallel to an upper surface of the substrate 100 and having an acuteangle with each of the second and third directions may be defined as athird direction.

Referring to FIGS. 1 and 2, the substrate (i.e., a semiconductor wafer)100 may include first and fourth regions I and IV, and the first regionI may include second and third regions II and III.

The substrate 100 may be a semiconductor wafer including silicon,germanium, silicon-germanium, or a III-V group compound semiconductor,such as GaP, GaAs, or GaSb. In example embodiments, the substrate 100may be a silicon-on-insulator (SOI) wafer or a germanium-on-insulator(GOI) wafer.

The first region I of the substrate 100 may be a chip region in whichpatterns for semiconductor chips may be formed. In example embodiments,a plurality of first regions I may be spaced apart from each other ineach of the first and second directions. Each of the first regions I mayinclude the second region II in which memory cells may be formed, andthus may be referred to as a cell region, and the third region IIIsurrounding the second region II in which peripheral circuit patternsfor driving the memory cells may be formed, and thus may be referred toas a peripheral circuit region.

The fourth region IV of the substrate 100 may be formed between thefirst regions I, and may be a scribe lane region to be cut forseparating the first regions I on the substrate 100 into semiconductorchips. In example embodiments, a test element group (TEG) for testingelectrical characteristics or failure of elements included in thesemiconductor chips, an alignment key or overlay key for aligning in aphoto process, etc., may be formed on the fourth region IV of thesubstrate 100. The alignment key may be used for aligning an exposuremask at a correct position over the substrate 100 in a photolithographyprocess, and the overlay key may be used for detecting overlay statusbetween a material pattern on the substrate 100 and a photoresistpattern thereon to correct the overlay and misalignment of thephotoresist pattern. The scribe line region may be disposed between eachadjacent pair of the first regions I, which are adjacent to each otherin both of the first and second directions. The scribe lines may belinearly extending regions denoting where the semiconductor wafer (afterformation of the semiconductor devices in the chip regions) may be cutto separate the resulting semiconductor chips from each other. Each ofthe resulting semiconductor chips may include the first region I and aportion of the scribe lane left after the separation. In some examples,the scribe lanes may have no circuitry (e.g., no transistors) that isnecessary for the operation of the resulting semiconductor devices (suchas no transistors, wires, etc. at all, or only dummy structures, such asone or more of dummy transistors, wires, etc.).

Hereinafter, the overlay key will be formed on the region W of thefourth region IV of the substrate 100, however, the inventive conceptmay not be limited thereto, and the alignment key may be formed on theregion W of the fourth region IV of the substrate 100.

Referring to FIGS. 3 to 5, first to third active patterns 105, 108 and109 may be formed on the second to fourth regions II, III and IV,respectively, of the substrate 100, and an isolation pattern 110 may beformed on the substrate 100 to cover sidewalls of the first to thirdactive patterns 105, 108 and 109.

The first to third active patterns 105, 108 and 109 may be formed byremoving an upper portion of the substrate 100 to form a first recess. Aplurality of first active patterns 105 may be spaced apart from eachother in the first and second directions. Each of the first activepatterns 105 may extend in the third direction.

The isolation pattern 110 may be formed by forming an isolation layer onthe substrate 100 to fill the first recess and planarizing the isolationlayer until upper surfaces of the first to third active patterns 105,108 and 109 may be exposed. In example embodiments, the planarizationprocess may include a chemical mechanical polishing (CMP) process and/oran etch back process.

After an impurity region is formed in the substrate 100 by performing,e.g., an ion implantation process, the first active pattern 105 and theisolation pattern 110 on the second region II of the substrate 100 maybe partially etched to form a second recess extending in the firstdirection.

A first gate structure 160 may be formed in the second recess. The firstgate structure 160 may include a first gate insulation layer 130 on asurface of the first active pattern 105 exposed by the second recess, afirst gate electrode 140 on the first gate insulation layer 130 to filla lower portion of the second recess, and a first gate mask 150 on thefirst gate electrode 140 to fill an upper portion of the second recess.The first gate structure 160 may extend in the first direction, and aplurality of first gate structures 160 may be spaced apart from eachother in the second direction.

The first gate insulation layer 130 may be formed by performing athermal oxidation process on the surface of the first active pattern 105exposed by the second recess, and thus may include, for example, siliconoxide.

Referring to FIGS. 6 to 8, a thermal oxidation process may be performedon an upper surface of the second active pattern 108 on the third regionIII of the substrate 100 to form a second gate insulation layer 600, andan insulation layer structure 200 may be formed on the first and thirdactive patterns 105 and 109 and the isolation pattern 110 on the secondand fourth regions II and IV of the substrate 100.

In example embodiments, the insulation layer structure 200 may includefirst, second, and third insulation layers 170, 180, and 190sequentially stacked. The first and third insulation layers 170 and 190may include oxide, e.g., silicon oxide, and the second insulation layer180 may include nitride, e.g., silicon nitride.

A first conductive layer 210 and a first mask 220 may be sequentiallyformed on the insulation layer structure 200. The first mask 220 mayinclude a first opening 230. The second gate insulation layer 600 andthe isolation pattern 110, and the first conductive layer 210 and theinsulation layer structure 200 may be etched using the first mask 220 asan etching mask to form a third recess 230R exposing the first activepattern 105 on the second region II of the substrate 100.

The first conductive layer 210 may include, for example, polysilicondoped with impurities, and the first mask 220 may include nitride, e.g.,silicon nitride.

During the etching process, upper portions of the first active pattern105, the isolation pattern 110 and the first gate mask 150 exposed bythe first opening 230 may also be etched to form the third recess 230R.For example, a bottom of the third recess 230R may be defined by arecessed surface of the first active pattern 105.

In example embodiments, the first opening 230 may expose an uppersurface of a central portion of each of the first active patterns 105extending in the third direction, and thus a plurality of third recesses230R may be formed in the first and second directions on the secondregion II of the substrate 100.

A second conductive layer 240 may be formed to fill the third recess230R.

In example embodiments, the second conductive layer 240 may be formed byforming a preliminary second conductive layer on the first activepattern 105, the isolation pattern 110, the first gate mask 150, and thefirst mask 220 to fill the third recess 230R, and removing an upperportion of the preliminary second conductive layer through a CMP processand/or an etch bask process. The second conductive layer 240 may have anupper surface substantially coplanar with an upper surface of the firstconductive layer 210.

In example embodiments, a plurality of second conductive layers 240 maybe spaced apart from each other in the first and second directions onthe second region II of the substrate 100. The second conductive layer240 may include, for example, doped polysilicon. In an exampleembodiment, the second conductive layer 240 may be merged with the firstconductive layer 210.

Referring to FIGS. 9 and 10, after removing the first mask 220, a thirdconductive layer 250, a barrier layer 270, and a first metal layer 280may be sequentially formed on the first and second conductive layers 210and 240.

In example embodiments, the third conductive layer 250 may include amaterial substantially the same as that of the first and secondconductive layers 210 and 240. For example, the third conductive layer250 may include doped polysilicon, and thus, in some embodiments, may bemerged with the first and second conductive layers 210 and 240. Thebarrier layer 270 may include metal nitride, e.g., titanium nitride,tantalum nitride, tungsten nitride, etc. The first metal layer 280 mayinclude metal, e.g., tungsten, titanium, tantalum, etc.

A second mask (not shown) may be formed to cover portions of the firstmetal layer 280 on the second and fourth regions II and IV of thesubstrate 100, and a second gate mask 618 may be formed to partiallycover a portion of the first metal layer 280 on the third region III ofthe substrate 100. After forming the second mask and the second gatemask 618, the first metal layer 280, the barrier layer 270, the thirdconductive layer 250, the first conductive layer 210 and the second gateinsulation layer 600 may be sequentially etched using the second maskand the second gate mask 618 as an etching mask.

Thus, a second gate structure 628 may be formed on the third region IIIof the substrate 100. The second gate structure 628 may include a secondgate insulation pattern 608, a second conductive pattern 218, a sixthconductive pattern 258, a second barrier pattern 278, a second metalpattern 288 and the second gate mask 618 sequentially stacked on thesecond active pattern 108. The second and sixth conductive patterns 218and 258 may include the same material, and thus may be merged with eachother to form a second gate electrode 268.

A gate spacer 630 may be formed to cover a sidewall of the second gatestructure 628, and impurities may be implanted into an upper portion ofthe second active pattern 108 adjacent to the second gate structure 628to form a source/drain layer 107.

After removing the second mask, a first insulating interlayer may beformed on the second to fourth regions II, III and IV of the substrate100, and may be planarized until the first metal layer 280 and thesecond gate mask 618 may be exposed to form a first insulatinginterlayer pattern 640 surrounding the second gate structure 628 and thegate spacer 630 on the third region III of the substrate 100. The firstinsulating interlayer pattern 640 may include an oxide, e.g., siliconoxide.

A capping layer 290 may be formed on the first metal layer 280, thefirst insulating interlayer pattern 640 and the second gate mask 618.The capping layer 290 may include nitride, e.g., silicon nitride.

Referring to FIGS. 11 to 13, a portion of the capping layer 290 on thesecond and fourth regions II and IV of the substrate 100 may be etchedto form first and third capping patterns 295 and 299, respectively, andthe first metal layer 280, the barrier layer 270, the third conductivelayer 250, the first and second conductive layers 210 and 240, and thethird insulation layer 190 may be sequentially etched using the firstand third capping patterns 295 and 299 as an etching mask.

In example embodiments, the first capping pattern 295 may extend in thesecond direction, and a plurality of first capping patterns 295 may bespaced apart from each other in the first direction on the second regionII of the substrate 100. Additionally, the third capping pattern 299 mayextend in the second direction, and a plurality of third cappingpatterns 299 may be spaced apart from each other in the first directionon the fourth region IV of the substrate 100. A portion of the cappinglayer 290 on the third region III of the substrate 100 may remain as asecond capping pattern 298.

By the etching process, on the second region II of the substrate 100, afourth conductive pattern 245, a fifth conductive pattern 255, a firstbarrier pattern 275, a first metal pattern 285, and the first cappingpattern 295 may be sequentially stacked on the first active pattern 105,the isolation pattern 110 and the first gate mask 150 in the thirdrecess 230R, and a third insulation pattern 195, a first conductivepattern 215, the fifth conductive pattern 255, the first barrier pattern275, the first metal pattern 285, and the first capping pattern 295 maybe sequentially stacked on the second insulation layer 180 of theinsulation layer structure 200 at an outside of the third recess 230R.

As illustrated above, the first to third conductive layers 210, 240 and250 may be merged with each other, and thus the fourth and fifthconductive patterns 245 and 255 sequentially stacked and the first andfifth conductive patterns 215 and 255 sequentially stacked may each forma first conductive structure 265. Hereinafter, the first conductivestructure 265, the first barrier pattern 275, the first metal pattern285, and the first capping pattern 295 sequentially stacked may bereferred to as a bit line structure 305.

In example embodiments, the bit line structure 305 may extend in thesecond direction on the second region II of the substrate 100, and aplurality of bit line structures 305 may be spaced apart from each otherin the first direction.

On the fourth region IV of the substrate 100, a sixth insulation pattern199, a third conductive pattern 219, a seventh conductive pattern 259, athird barrier pattern 279, a third metal pattern 289 and a third cappingpattern 299 may be sequentially stacked on the second insulation layer180 of the insulation layer structure 200. The third and seventhconductive patterns 219 and 259 sequentially stacked may form a secondconductive structure 269. Hereinafter, the sixth insulation pattern 199,the second conductive structure 269, the third barrier pattern 279, thethird metal pattern 289 and the third capping pattern 299 sequentiallystacked may be referred to as a key structure 309.

In example embodiments, the key structure 309 may extend in the seconddirection on the fourth region IV of the substrate 100, and a pluralityof key structures 309 may be spaced apart from each other in the firstdirection. An upper surface of the key structure 309 may besubstantially coplanar with an upper surface of the bit line structure305. In an exemplary embodiment, the key structure 309 and the bit linestructure 305 may be formed, using a same process, from a stack of thefirst metal layer 280, the barrier layer 270, the third conductive layer250, the first conductive layer 210 (or merged with the secondconductive layer 240).

A first trench 705 may be formed between neighboring ones of the bitline structures 305 on the second region II of the substrate 100 toextend in the second direction, and may expose an upper surface of thesecond insulation layer 180 to be connected with the third recess 230R.The first trench 705 may have a first width W1 in the first direction.Additionally, a second trench 709 may be formed between neighboring onesof the key structures 309 on the fourth region IV of the substrate 100to extend in the second direction. The second trench 709 may expose anupper surface of the second insulation layer 180, and may have a secondwidth W2 greater than the first width W1 in the first direction. Forexample, a distance between the key structures 309 spaced apart fromeach other in the first direction may be greater than a distance betweenthe bit line structures 305 spaced apart from each other in the firstdirection. In example embodiments, the second trench 709 may have avertical sidewall substantially perpendicular to the upper surface ofthe substrate 100.

Referring to FIGS. 14 and 15, a first spacer layer may be formed onupper surfaces of the first active pattern 105, the isolation pattern110 and the first gate mask 150 exposed by the third recess 230R, asidewall of the third recess 230R, the second insulation layer 180, andthe second and third capping patterns 298 and 299 to cover the bit linestructure 305 and the key structure 309, and fourth and fifth insulationlayers may be sequentially formed on the first spacer layer.

The first spacer layer may also cover a sidewall of the third insulationpattern 195 between the second insulation layer 180 and the bit linestructure 305, and the fifth insulation layer may fill the third recess230R.

The fourth and fifth insulation layers may be etched by an etchingprocess. In example embodiments, the etching process may be performed bya wet etch process, and other portions of the fourth and fifthinsulation layers except for a portion in the third recess 230R may beremoved. Thus, most of an entire surface of the first spacer layer, forexample, an entire surface except for a portion thereof in the thirdrecess 230R may be exposed, and portions of the fourth and fifthinsulation layers remaining in the third recess 230R may form seventhand eighth insulation patterns 320 and 330, respectively.

A second spacer layer may be formed on the exposed surface of the firstspacer layer and the seventh and eighth insulation patterns 320 and 330in the third recess 230R, and may be anisotropically etched to formthird and fourth spacers 340 and 349 on the surface of the first spacerlayer and the seventh and eighth insulation patterns 320 and 330 tocover a sidewall of the bit line structure 305 and a sidewall of the keystructure 309, respectively. The third and fourth spacers 340 and 349may include an oxide, e.g., silicon oxide.

A dry etching process may be performed using the first to third cappingpatterns 295, 298 and 299 and the third and fourth spacers 340 and 349as an etching mask to form a third trench 350 exposing the upper surfaceof the first active pattern 105 on the second region II of the substrate100. In an example embodiment, the dry etching process may be a part ofan etching process of forming the third and fourth spacers 340 and 349.The upper surface of the isolation pattern 110 and the upper surface ofthe first gate mask 150 may also be exposed by the third trench 350.Additionally, by the dry etching process, the second trench 709 may beenlarged downwardly to expose an upper surface of the isolation pattern110 on the fourth region IV of the substrate 100.

By the dry etching process, portions of the first spacer layer on uppersurfaces of the first to third capping patterns 295, 298 and 299 and anupper surface of the second insulation layer 180 may be removed, andthus a first spacer 315 covering the sidewall of the bit line structure305 and a second spacer 319 covering the sidewall of the key structure309 may be formed. The first and second spacers 315 and 319 may includenitride, e.g., silicon nitride. Additionally, during the dry etchingprocess, the first and second insulation layers 170 and 180 may bepartially removed, such that first and second insulation patterns 175and 185 may remain under the bit line structure 305, and fourth andfifth insulation patterns 179 and 189 may remain under the key structure309. The first to third insulation patterns 175, 185 and 195 that aresequentially stacked under the bit line structure 305 may form a firstinsulation pattern structure, and fourth to sixth insulation patterns179, 189 and 199 that are sequentially stacked under the key structure309 may form a second insulation pattern structure.

A third spacer layer may be formed on the upper surfaces of the first tothird capping patterns 295, 298 and 299, outer sidewalls of the thirdand fourth spacers 340 and 349, portions of upper surfaces of theseventh and eighth insulation patterns 320 and 330, and the uppersurfaces of the first active pattern 105, the isolation pattern 110 andthe first gate mask 150 exposed by the third trench 350, and may beanisotropically etched to form a fifth spacer 375 covering the sidewallof the bit line structure 305 and a sixth spacer 379 covering thesidewall of the key structure 309. The fifth and sixth spacers 375 and379 may include nitride, e.g., silicon nitride.

The first, third and fifth spacers 315, 340 and 375 sequentially stackedin a horizontal direction substantially parallel to the upper surface ofthe substrate 100 from the sidewall of the bit line structure 305 on thesecond region II of the substrate 100 may be referred to as a firstpreliminary spacer structure, and the second, fourth and sixth spacers319, 349 and 379 sequentially stacked in the horizontal direction fromthe sidewall of the key structure 309 on the fourth region IV of thesubstrate 100 may be referred to as a second spacer structure.

A second insulating interlayer may be formed on the substrate 100 tocover the bit line structure 305, the key structure 309, the secondcapping pattern 298, the first preliminary spacer structure and thesecond spacer structure, and an upper portion of the second insulatinginterlayer may be planarized until the upper surfaces of the first tothird capping patterns 295, 298 and 299 may be exposed, and an upperportion of the second insulating interlayer in the third recess 230R andthe first trench 705 on the second region II of the substrate 100 may beremoved to form a second insulating interlayer pattern 710 filling thesecond trench 709 on the fourth region IV of the substrate 100. Thesecond insulating interlayer pattern 710 may include oxide, e.g.,silicon oxide.

Referring to FIGS. 16 and 17, an upper portion of the first activepattern 105 may be removed by an etching process to form a fourth recess390 connected to the third trench 350.

The second insulating interlayer pattern 710 on the fourth region IV ofthe substrate 100 may be removed to form the second trench 709 again,and an upper portion of the isolation pattern 110 under the secondinsulating interlayer pattern 710 may be partially etched. Thus, abottom of the second trench 709 may be lower than that of each of thekey structures 309 and may also be lower than an upper surface of thethird active pattern 109.

A lower contact plug layer 400 may be formed to fill the third trench350 and the fourth recess 390 on the second region II of the substrate100 and the second trench 709 on the fourth region IV of the substrate100.

The bit line structures 305 having the first preliminary spacerstructures on the respective sidewalls thereof may be spaced apart fromeach other in the first direction on the second region II of thesubstrate 100, and the key structures 309 having the second spacerstructures on the respective sidewalls thereof may be spaced apart fromeach other in the first direction on the fourth region IV of thesubstrate 100. Thus, the lower contact plug layer 400 may have an unevenupper surface.

Particularly, a width in the first direction of the third trench 350 maybe less than the first width W1 in the first direction of the firsttrench 705 (refer to FIG. 12), and thus may be much less than the secondwidth W2 in the first direction of the second trench 709. Accordingly,the lower contact plug layer 400 may not entirely fill the third trench350 on the second region II of the substrate 100 to form a first air gap40. An upper surface of a portion of the lower contact plug layer 400 onthe second trench 709 may be much lower than an upper surface of aportion of the lower contact plug layer 400 on the key structure 309 onthe fourth region IV of the substrate 100.

In example embodiments, the lower contact plug layer 400 may include aconductive material, e.g., doped polysilicon.

Referring to FIGS. 18 and 19, a melting process may be performed on thelower contact plug layer 400.

In example embodiments, the melting process may include a laserannealing process.

In the laser annealing process, the lower contact plug layer 400 may beheated such that the heated lower contact plug layer 400 flows toannihilate the first air gap 40 between the bit line structures 305, andthe uneven upper surface of the lower contact plug layer 400 may beconsiderably planarized. In an example embodiment, the height differencebetween the upper surface of the portion of the lower contact plug layer400 on the second trench 709 and the upper surface of the portion of thelower contact plug layer 400 on the key structure 309 may be relieved onthe fourth region IV of the substrate 100.

In an example embodiment, the melting process may cause the uppersurface of the lower contact plug layer 400 to have a wave-like shape.

Referring to FIGS. 20 and 21, an upper portion of the lower contact pluglayer 400 may be planarized until the upper surfaces of the first tothird capping patterns 295, 298 and 299 may be exposed. Thus, apreliminary lower contact plug 405P may be formed between the bit linestructures 305, and a filling pattern 409 may be formed between the keystructures 309.

The planarization process may include a CMP process. As illustratedabove, since the height difference between the upper surfaces ofportions of the lower contact plug layer 400 has been relieved, each ofthe preliminary lower contact plug 405P and the filling pattern 409 mayhave a flat upper surface. The upper surface of the preliminary lowercontact plug 405P between the bit line structures 305 may besubstantially coplanar with the upper surfaces of the bit linestructures 305, and the upper surface of the filling pattern 409 betweenthe key structures 309 may be substantially coplanar with the uppersurfaces of the key structures 309. Accordingly, since the uppersurfaces of the bit line structures 305 and the upper surfaces of thekey structures 309 have the substantially the same height, the uppersurface of the preliminary lower contact plug 405P and the upper surfaceof the filling pattern 409 may have substantially the same height.

In example embodiments, each of the preliminary lower contact plug 405Pand the filling pattern 409 may extend in the second direction, and aplurality of preliminary lower contact plugs 405P may be formed to bespaced apart from each other in the first direction.

Referring to FIGS. 22 and 23, a third mask (not shown) including fourthopenings, each of which may extend in the first direction, spaced apartfrom each other in the second direction may be formed on the first tothird capping patterns 295, 298 and 299, the preliminary lower contactplug 405P and the filling pattern 409, and a portion of the preliminarylower contact plug 405P may be etched to form a lower contact plug 405using the third mask as an etching mask.

In example embodiments, each of the fourth openings may overlap theportion of the preliminary lower contact plug 405P on the first gatestructure 160 in a vertical direction substantially perpendicular to theupper surface of the substrate 100 on the second region II of thesubstrate 100. By the etching process, the portion of the preliminarylower contact plug 405P may be removed to expose the upper surface ofthe first gate mask 150 of the first gate structure 160 between the bitline structures 305 on the second region II of the substrate 100.

After removing the third mask, a fourth capping pattern 410 may beformed on the exposed first gate mask 150 on the second region II of thesubstrate 100 to fill a space between the two neighboring bit linestructures 305. The fourth capping pattern 410 may include nitride,e.g., silicon nitride. In example embodiments, the fourth cappingpattern 410 may extend in the first direction between the bit linestructures 305, and a plurality of fourth capping patterns 410 may beformed in the second direction.

Thus, the lower contact plug 405 extending in the second directionbetween the bit line structures 305 may be divided into a plurality ofpieces spaced apart from each other in the second direction by thefourth capping patterns 410 on the second region II of the substrate100. For example, the lower contact plug 405 and the fourth cappingpattern 410 may be arranged alternately in the second direction.

Referring to FIGS. 24 and 25, upper portions of the lower contact plug405 and the filling pattern 409 may be removed.

In example embodiments, the upper portions of the lower contact plug 405and the filling pattern 409 may be removed by an etch back process. Asillustrated above, the upper surfaces of the lower contact plug 405 andthe filling pattern 409 may have the same height. After the etch backprocess is completed, each of the lower contact plug 405 and the fillingpattern 409 may have a predetermined thickness.

As the upper portion of the lower contact plug 405 is removed, an upperportion of the first preliminary spacer structure on the sidewall of thebit line structure 305 may be exposed, and upper portions of the thirdand fifth spacers 340 and 375 of the exposed first preliminary spacerstructure may be removed.

An etch back process may be further performed to remove upper portionsof the lower contact plug 405 and the filling pattern 409. Thus, theupper surface of the lower contact plug 405 may be lower than uppermostsurfaces of the third and fifth spacers 340 and 375.

By the etch back process, the upper portions of the lower contact plug405 and the filling pattern 409 may be removed and lower portionsthereof may remain, and the upper surfaces of the remaining portions ofthe lower contact plug 405 and the filling pattern 409 may be flat.However, due to the width difference between the lower contact plug 405and the filling pattern 409, the upper surfaces of the lower contactplug 405 and the filling pattern 409 may not be coplanar with eachother. For example, by the etch back process, the filling pattern 409having a relatively large width when compared to the lower contact plug405 having a relatively small width may be less etched, and thus theupper surface of the filling pattern 409 may be higher than the uppersurface of the lower contact plug 405 after the etch back process.

A fourth spacer layer may be formed on the bit line structure 305, thefirst preliminary spacer structure, the second to fourth cappingpatterns 298, 299 and 410, the lower contact plug 405 and the fillingpattern 409, and may be anisotropically etched so that a seventh spacer425 may be formed to cover the first, third and fifth spacers 315, 340and 375 on each of opposite sidewalls of the bit line structure 305 inthe first direction and an upper surface of the lower contact plug 405may be exposed without being covered by the seventh spacer 425.

First and second metal silicide patterns 435 and 439 may be formed onthe exposed upper surfaces of the lower contact plug 405 and the fillingpattern 409. In example embodiments, the first and second metal silicidepatterns 435 and 439 may be formed by forming a second metal layer onthe first to fourth capping patterns 295, 298, 299 and 410, the seventhspacer 425, the lower contact plug 405 and the filling pattern 409,thermally treating the second metal layer, and removing unreactedportion of the second metal layer. The first and second metal silicidepatterns 435 and 439 may include, e.g., cobalt silicide, nickelsilicide, titanium silicide, etc.

Referring to FIGS. 26 and 27, a first sacrificial layer may be formed onthe first to fourth capping patterns 295, 298, 299 and 410, the seventhspacer 425, and the first and second metal silicide patterns 435 and439, the first sacrificial layer may be planarized until the uppersurfaces of the first to fourth capping patterns 295, 298, 299 and 410may be exposed, and a first hole H1 may be formed on the third regionIII of the substrate 100.

The first sacrificial layer may include, e.g., silicon-on-hardmask(SOH), amorphous carbon layer (ACL), etc.

The first hole H1 may extend through the second capping pattern 298 andthe first insulating interlayer pattern 640 to expose an upper surfaceof the source/drain layer 107 on the third region III of the substrate100.

After removing the first sacrificial layer, an upper contact plug layer450 may be formed on the first to fourth capping patterns 295, 298, 299and 410, the first, third, fifth and seventh spacers 315, 340, 375 and425, the first and second metal silicide patterns 435 and 439, the lowercontact plug 405, the filling pattern 409 and the source/drain layer107.

The bit line structures 305 having the first, third, fifth and seventhspacers 315, 340, 375 and 425 on sidewalls thereof may be spaced apartfrom each other in the first direction on the second region II of thesubstrate 100, and may have an upper surface higher than that of thefirst metal silicide pattern 435. The key structures 309 may be formedon the fourth region IV of the substrate 100 and may have an uppersurface higher than that of the second metal silicide pattern 439. Thus,an upper surface of the upper contact plug layer 450 may have an unevenupper surface.

In example embodiments, the upper contact plug layer 450 may beconformally formed on the key structures 309 and the second metalsilicide pattern 439 on the fourth region IV of the substrate 100. Thus,an upper surface of a portion of the upper contact plug layer 450 on thesecond metal silicide pattern 439 may be lower than an upper surface ofa portion of the upper contact plug layer 450 on the key structure 309.

In example embodiments, the upper contact plug layer 450 may includemetal, e.g., tungsten.

Referring to FIGS. 28 and 29, an upper portion of the upper contact pluglayer 450 may be planarized by a CMP process.

The CMP process may be performed such that an upper surface of the uppercontact plug layer 450 may be higher than those of the bit linestructures 305 and the key structures 309. For example, no polishingstop layer may be used, and thus it may be difficult to control time forthe CMP process. However, there is a height difference between uppersurfaces of portions of the upper contact plug layer 450 on the secondmetal silicide pattern 439 and the key structure 309, and thus the timefor the CMP may be controlled by using the height difference.

By the CMP process, a portion of the upper contact plug layer 450 on thesecond and third regions II and III of the substrate 100 may have a flatupper surface, and a portion of the upper contact plug layer 450 on thefourth region IV of the substrate 100 may have a constant thickness onupper surfaces of the key structures 309 and the second metal silicidepattern 439. A third trench 720 may be defined by the upper contact plug450 on the fourth region IV of the substrate 100. For example, the thirdtrench 720 may be defined by an uneven upper surface of the uppercontact plug 450. The upper contact plug 450 may be disposed on an uppersidewall and an upper surface of the key structure 309 and an uppersurface of the second metal silicide pattern 439. The third trench 720may have a flat bottom and a sidewall that may be close to a rightangle, for example, an angle equal to or more than 75 degrees withrespect to the upper surface of the substrate 100. For example, asidewall of a portion of the upper contact plug layer 450 on the uppersidewall of the key structure 309 may be almost vertical.

A slurry particle 730 used in the CMP process may not be entirelyremoved but partially remain, and for example, may remain in the thirdtrench 720 having a concave shape. The slurry particle 730 may include,e.g., silicon oxide.

Referring to FIG. 30, a cleansing process may be performed to removeimpurities generated in the CMP process.

By the cleansing process, the slurry particle 730 remaining in the thirdtrench 720 may be removed. In an exemplary embodiment, the third trench720 may have a depth smaller than that of the second trench 709 (referto FIG. 13) by the filling pattern 409 and the second metal silicidepattern 439, and thus an upper portion of the slurry particle 730 may beexposed above the third trench 720, so as to be easily removed by thecleansing process. In an example embodiment, the depth of the thirdtrench 720 may be smaller than a diameter of a slurry particle for theCMP process.

Referring to FIGS. 31 and 32, a portion of the upper contact plug layer450 on the second region II of the substrate 100 may be etched to form asecond hole 470, and a portion of the upper contact plug layer 450 onthe third region III of the substrate 100 may be patterned.

The second hole 470 may be formed by removing an upper portion of theupper contact plug layer 450, an upper portion of the first cappingpattern 295, and upper portions of the first, fifth and seventh spacers315, 375 and 425 on the second region II of the substrate 100, and mayexpose an upper surface of the third spacer 340.

The second hole 470 may divide the upper contact plug layer 450 into aplurality of upper contact plugs 455 on the second region II of thesubstrate 100. In example embodiments, the plurality of upper contactplugs 455 may be formed in the first and second directions and may bearranged in a honeycomb pattern in a plan view. Each of the uppercontact plugs 455 may have a shape of a circle, an ellipse, or apolygon.

The lower contact plug 405, the first metal silicide pattern 435 and theupper contact plug 455 sequentially stacked on the second region II ofthe substrate 100 may form a first contact plug structure.

As the upper contact plug layer 450 is patterned on the third region IIIof the substrate 100, a second contact plug 457 filling the first holeH1 and a wiring 458 contacting an upper surface of the second contactplug 457 may be formed. The second contact plug 457 and the wiring 458may be electrically connected to the source/drain layer 107. In anexample embodiment, the wiring 458 may be electrically connected to thebit line structure 305 on the second region II of the substrate 100, andmay apply electrical signals to the bit line structure 305. The term“contact,” as used herein, refers to a direct connection (i.e.,touching) unless the context indicates otherwise.

In example embodiments, during the formation of the wiring 458, thethird trench 720 may serve as an overlay key in a photolithographyprocess for patterning the upper contact plug layer 450. For example, amask for the photolithography process may be aligned to a semiconductorwafer using the third trench 720 as the overlay key. As illustratedabove, the third trench 720 with an almost vertical sidewall may serveas the overlay key.

A portion of the upper contact plug layer 450 remaining on the fourthregion IV of the substrate 100 may be referred to as a third conductivestructure 459.

Referring to FIGS. 33 and 34, the third spacer 340 exposed by the secondhole 470 may be removed to form a second air gap 345 connected to thesecond hole 470. The third spacer 340 may be removed by, e.g., a wetetching process. The term “air” as discussed herein, may refer toatmospheric air, or other gases that may be present during themanufacturing process.

In example embodiments, not only a portion of the third spacer 340 onthe sidewall of the bit line structure 305 extending in the seconddirection directly exposed by the second hole 470 but also otherportions of the third spacer 340 parallel to the directly exposedportion thereof in the horizontal direction may be removed. For example,not only the portion of the third spacer 340 exposed by the second hole470 not to be covered by the upper contact plug 455 but also a portionof the third spacer 340 adjacent to the exposed portion in the seconddirection to be covered by the fourth capping pattern 410 and a portionof the third spacer 340 adjacent to the exposed portion in the seconddirection to be covered by the upper contact plug 455 may be all removedto form the second air gap 345.

Third and fourth insulating interlayers 480 and 490 may be sequentiallystacked to fill the second hole 470 on the second region II of thesubstrate 100, a space between the wirings 458 on the third region IIIof the substrate 100, and the third trench 720 on the fourth region IVof the substrate 100. The third and fourth insulating interlayers 480and 490 may also be sequentially stacked on the fourth capping pattern410.

The third insulating interlayer 480 may include a material having a lowgap filling characteristic, and thus the second air gap 345 under thesecond hole 470 may not be filled. The second air gap 345 may also bereferred to as an air spacer 345 and may form a first spacer structuretogether with the first, fifth and seventh spacers 315, 375 and 425. Forexample, the second air gap 345 may be a spacer including an air. Thefourth insulating interlayer 490 may include nitride, e.g., siliconnitride.

Referring to FIGS. 35 to 37, a capacitor 540 may be formed to contactthe upper surface of the upper contact plug 455.

In an example embodiment, an etch stop layer 500 and a mold layer (notshown) may be sequentially formed on the upper contact plug 455, thethird and fourth insulating interlayers 480 and 490, the wiring 458 andthe third conductive structure 459, and partially etched to form a sixthopening partially exposing the upper surface of the upper contact plug455.

A lower electrode layer (not shown) may be formed on a sidewall of thesixth opening, the exposed upper surface of the upper contact plug 455and the mold layer, a second sacrificial layer (not shown) may be formedon the lower electrode layer to fill the sixth opening, and the lowerelectrode layer and the second sacrificial layer may be planarized untilan upper surface of the mold layer may be exposed to divide the lowerelectrode layer. The second sacrificial layer and the mold layer may beremoved by, e.g., a wet etching process, and thus a lower electrode 510having a cylindrical shape may be formed on the exposed upper surface ofthe upper contact plug 455. Alternatively, the lower electrode 510 mayhave a pillar shape filling the sixth opening.

A dielectric layer 520 may be formed on a surface of the lower electrode510 and the etch stop layer 500, and an upper electrode 530 may beformed on the dielectric layer 520 so that the capacitor 540 includingthe lower electrode 510, the dielectric layer 520 and the upperelectrode 530 may be formed.

A fifth insulating interlayer 550 may be formed to cover the capacitor540 on the second to fourth regions II, III and IV of the substrate 100.The fifth insulating interlayer 550 may include oxide, e.g., siliconoxide. Upper wirings (not shown) may be further formed to formsemiconductor chips on the respective first regions I of the substrate100.

A dicing process or a sawing process may be performed so that thesemiconductor chips on the respective first regions I of the substrate100 may be divided, and thus the fabrication of the semiconductor devicemay be completed.

FIG. 38 shows only a portion of the semiconductor device taken along aline D-E of FIG. 2 remains according to the partial removal of thesemiconductor device on the region W in the fourth region IV of thesubstrate 100 by the dicing process.

As illustrated above, the lower contact plug layer 400 filling the firsttrench 705 between the bit line structures 305 may fill the secondtrench 709 between the key structures 309 on the fourth region IV of thesubstrate 100, and the upper surface of the portion of the lower contactplug layer 400 on the second trench 709 may be lower than the uppersurface of the portion of the lower contact plug layer 400 on the keystructures 309. However, before the CMP process is performed on thelower contact plug layer 400, a melting process, e.g., a laser annealingprocess, may be performed so that the height difference between portionsof the lower contact plug layer 400 on the fourth region IV of thesubstrate 100 may decrease. Thus, the CMP process may be performed untilthe upper surfaces of the bit line structures 305 and the key structures309 may be exposed, so that the upper surface of the filling pattern 409in the second trench 709 may be substantially flat and substantiallycoplanar with the upper surfaces of the key structures 309.

Even though an etch back process is performed on the filling pattern409, the filling pattern 409 may not be entirely removed, and at least alower portion thereof may remain in the second trench 709 so that adepth of the second trench 709 may decrease and that the flatness of theupper surface of the filling pattern 409 may be kept. Thus, the uppercontact plug layer 450 may be formed on the lower contact plug 405 andthe filling pattern 409, and a CMP process may be performed on the uppercontact plug layer 450, so that the third trench 720 on a portion of theupper contact plug layer 450 on the second trench 709 may have a depthsmaller than that of the second trench 709. Accordingly, the slurryparticle 730 remaining in the third trench 720 after the CMP process maybe easily removed by the cleansing process, and thus may not damageother structures in subsequent processes.

Additionally, the third trench 720 on the upper contact plug layer 450,which may be conformally formed on the filling pattern 409 filling alower portion of the second trench 709 having a vertical sidewall andhaving a flat upper surface and the second metal silicide pattern 439thereon, may have an almost vertical sidewall, and when the wiring 458is formed by patterning the upper contact plug layer 450, the thirdtrench 720 may serve as an overlay key.

Up to this point, the lower contact plug layer 400 including aconductive material, e.g., doped polysilicon, fills the first trench 705between the bit line structures and the second trench 709 between thekey structures 309, however, the inventive concept may not be limitedthereto.

For example, if first structures (e.g., bit line structures 305) andsecond structures (e.g., key structures 309) are formed on the secondand fourth regions II and IV, respectively, of the substrate 100, andthe second with W2 of the second trench 709 between the secondstructures is greater than the first width W1 of the first trench 705between the first structures, a filling layer may be formed to fill thefirst trench 705 and the second trench 709, a melting process, e.g., alaser annealing process, may be performed on the filling layer todecrease the height difference of portions of the filling layer, and thefilling layer may be planarized by a CMP process, such that first andsecond filling patterns may be formed in the first trench 705 and thesecond trench 709, respectively, to have substantially coplanar uppersurfaces. The filling layer may include a conductive material. Thepresent invention is not limited thereto. In an example embodiment, thefilling layer may include any material that flows in the melting processso that a height difference is relieved. For example, the filling layermay include polysilicon, oxide, nitride, etc.

Upper portions of the first and second filling patterns may be removed,a conductive layer may be conformally formed on the first and secondfilling patterns, and may be planarized by a CMP process, such that aconductive structure having an almost vertical sidewall and the shallowthird trench 720 may be formed on the second filling pattern in thesecond trench 709. Accordingly, even if the slurry particle 730 used inthe CMP process remains in the third trench 720, the slurry particle 730may be easily removed by a cleansing process, and the conductivestructure may also serve as an overlay key.

The semiconductor device manufactured by the above method may have thefollowing structural features.

The semiconductor device may include the chip region I having the cellregion II and the peripheral circuit region III at least partiallysurrounding the cell region II, and the scribe lane region IVsurrounding the chip region I. The first to third active patterns 105,108 and 109, which may be defined by the isolation pattern 110, may beformed on the cell region II, the peripheral circuit region III and thescribe lane region IV, respectively, of the substrate 100.

The semiconductor device may include the first gate structures 160 eachof which may be buried in an upper portion of the first active pattern105, the bit line structures 305 on the cell region II of the substrate100, the first contact plug structures on the respective first activepatterns 105 between the bit line structures 305, and the capacitors 540on the respective first contact plug structures. Each of the firstcontact plug structures may include the lower and upper contact plugs405 and 455 sequentially stacked.

Additionally, the semiconductor device may include the second gatestructure 628 on the second active pattern 108 on the peripheral circuitregion III of the substrate 100, the second contact plug 457 on thesecond active pattern 108 adjacent to the second gate structure 628, andthe wiring 458 on the second contact plug 457.

Furthermore, the semiconductor device may include the key structures 309having the same stacked structure as the bit line structures 305 andhaving the upper surfaces substantially coplanar with the upper surfacesof the bit line structures 305, which may be spaced apart from eachother by the second trench 709, on the scribe lane region IV of thesubstrate 100, the filling pattern 409 having a flat surface andincluding a conductive material in the lower portion of the secondtrench 709, and the third conductive structure 459 on the upper sidewallof the second trench 709 and the upper surfaces of the key structures309.

In example embodiments, the third conductive structure 459 may have aconstant thickness, and a sidewall of a portion of the third conductivestructure 459 on the upper sidewall of the second trench 709 may have anangle equal to or more than about 75 degrees with respect to the uppersurface of the substrate 100.

In example embodiments, a distance between the key structures 309 may begreater than that of the bit line structures 305.

In example embodiments, the lower contact plug 405 may include the samematerial as the filling pattern 409, and the upper contact plug 455 mayinclude the same material as that of the wiring 458 and the thirdconductive structure 459. An upper surface of the upper contact plug 455may be substantially coplanar with those of the wiring 458 and the thirdconductive structure 459. In an example embodiment, the wiring 458 maybe electrically connected to the bit line structure 305 to applyelectrical signals thereto.

In example embodiments, the first metal silicide pattern 435 may beformed between the lower and upper contact plugs 405 and 455, and thesecond metal silicide pattern 439 may be formed between the fillingpattern 409 and the third conductive structure 459. The first and secondmetal silicide patterns 435 and 439 may include the same material.

In example embodiments, the second, fourth and sixth spacers 319, 349and 379 including nitride, oxide and nitride, respectively, may besequentially stacked in the horizontal direction on the sidewall of eachof the key structures 309.

Each of the key structures 309 may be formed on the third active pattern109 and the isolation pattern 110, and the filling pattern 409 may beformed on the isolation pattern 110. In example embodiments, a bottomsurface of the filling pattern 409 may be lower than those of the keystructures 309 and may be lower than an upper surface of the thirdactive pattern 109.

FIGS. 39 to 42 are cross-sectional views illustrating a method ofmanufacturing a semiconductor device according to a comparativeembodiment. FIG. 39 includes cross-sections taken along lines A-A′ andB-B′ of a region Y of a corresponding plan view, and FIGS. 40 to 42include cross-sections taken along lines C-C′ and D-D′ of regions Z andW of corresponding plan views.

This method may include processes substantially the same as or similarto those illustrated with reference to FIGS. 1 to 38, and thusrepetitive descriptions thereon are omitted herein.

Referring to FIGS. 39 and 40, processes substantially the same as orsimilar to those illustrated with reference to FIGS. 1 to 17 may beperformed, and without performing the melting process illustrated withreference to FIGS. 18 and 19, the CMP process illustrated with referenceto FIGS. 20 and 21 may be performed.

On the fourth region IV of the substrate 100, a height of an uppersurface of the lower contact plug layer 400 on the second trench 709 maybe much less than a height of an upper surface of the lower contact pluglayer 400 on the key structure 309, and thus an upper surface of thefilling pattern 409 remaining in the second trench 709 may be concave,so that a fifth recess 403 may be formed on the filling pattern 409.

Referring to FIG. 41, processes substantially the same as or similar toFIGS. 22 to 25 may be performed.

When the upper portion of the lower contact plug 405 is removed by theetch back process, the filling pattern 409 remaining in the secondtrench 709 may be partially removed, and since the concave fifth recess403 is formed on the filling pattern 409, a central portion of thefilling pattern 409 may be entirely removed by the etch back process toform a third trench 404 exposing an upper surface of the secondinsulation layer 180.

The second metal silicide pattern 439 may be further formed on the uppersurface of the remaining filling pattern 409.

Referring to FIG. 42, processes substantially the same as or similar toFIGS. 26 to 29 may be performed.

For example, the upper contact plug layer 450 may be formed on the firstand second metal silicide patterns 435 and 439, and a CMP process may beperformed on the upper contact plug layer 450. A portion of the uppercontact plug layer 450 on the fourth region IV of the substrate 100 mayhave a constant thickness on the second insulation layer 180, the secondmetal silicide pattern 439 and the key structures 309 with a largeheight difference between a portion on the second insulation layer 180and a portion on the key structures 309. Additionally, the third trench720 on the upper contact plug layer 450 may have a slanted sidewall withrespect to the upper surface of the substrate 100, and the slurryparticle 730 used in the CMP process may not be entirely removed butpartially remain.

The cleansing process illustrated with reference to FIG. 30 may beperformed, however, only a portion of the slurry particle 730 stuck inthe deep third trench 720 may be removed, and most portion thereof mayremain in the third trench 720. Thus, the remaining slurry particle 730may damage other layer structures.

As the third trench 720 has the slanted sidewall, the process forpatterning the upper contact plug layer 450 using the third trench 720as an overlay key to form the wiring 458 may have alignment problemsunlike the process as described with reference to FIGS. 31 and 32.

Unlike the comparative embodiment, in the method of manufacturing thesemiconductor device in accordance with example embodiments, beforeforming the CMP process on the lower contact plug layer 400, a meltingprocess, e.g., a laser annealing process may be performed so as todecrease the height difference, and by the etch back process, thefilling pattern 409 may fill a lower portion of the second trench 709and have a flat upper surface.

Accordingly, since the third trench 720 on the upper contact plug layer450 may not be deep, the slurry particle 730 remaining after the CMPprocess may not be stuck in the third trench 720, and thus may be easilyremoved by the cleansing process. Additionally, the third trench 720 mayhave an almost vertical sidewall, and thus the wiring 458 may be easilyformed by using the third trench 720 as an overlay key.

While the present inventive concepts have been shown and described withreference to example embodiments thereof, it will be understood by thoseof ordinary skill in the art that various changes in form and detailsmay be made thereto without departing from the spirit and scope of thepresent inventive concepts as set forth by the following claims.

What is claimed is:
 1. A semiconductor device comprising: a substrateincluding: a chip region; and a scribe lane region surrounding the chipregion; a bit line structure on the chip region of the substrate, thebit line structure having a stacked structure including multiple layersstacked on each other; a first spacer structure on a sidewall of the bitline structure; a key structure on the scribe lane region of thesubstrate, the key structure having the same stacked structure as thebit line structure; a second spacer structure on a sidewall of the keystructure; a filling pattern on the scribe lane region of the substrate,the filling pattern being adjacent to the second spacer structure andincluding a conductive material; and a first conductive structure on thefilling pattern, the key structure and the second spacer structure. 2.The semiconductor device according to claim 1, wherein the second spacerstructure has the same stacked structure as the first spacer structure.3. The semiconductor device according to claim 2, wherein each of thefirst and second spacer structures includes first, second and thirdspacers, the first, second and third spacers including nitride, oxideand nitride, respectively.
 4. The semiconductor device according toclaim 1, further comprising a metal silicide pattern between the fillingpattern and the first conductive structure.
 5. The semiconductor deviceaccording to claim 4, wherein the first conductive structure covers anupper surface of the metal silicide pattern, an outer sidewall and anupper surface of the second spacer structure, and an upper surface ofthe key structure.
 6. The semiconductor device according to claim 1,wherein: the filling pattern includes doped polysilicon, and the firstconductive structure includes metal.
 7. The semiconductor deviceaccording to claim 1, wherein each of the key structure and the bit linestructure includes an insulation pattern structure, a second conductivestructure, a barrier pattern, a metal pattern and a capping patternsequentially stacked on the substrate.
 8. The semiconductor deviceaccording to claim 1, further comprising an isolation pattern on thesubstrate, wherein: an active pattern is defined at an upper portion ofthe substrate, a sidewall of the active pattern is covered by theisolation pattern, the key structure is disposed on the active patternand the isolation pattern, and the filling pattern is disposed on theisolation pattern.
 9. The semiconductor device according to claim 1,further comprising a contact plug structure adjacent to the bit linestructure, wherein the contact plug structure includes a lower contactplug and an upper contact plug sequentially stacked.
 10. Thesemiconductor device according to claim 9, wherein: the lower contactplug includes the same material as the filling pattern, and the uppercontact plug includes the same material as the first conductivestructure.
 11. A semiconductor device comprising: a substrate including:a first region; and a second region surrounding the first region, thesubstrate including first and second active patterns on the first regionand the second region, respectively, the first and second activepatterns being defined by an isolation pattern on the substrate; a firstgate structure in an upper portion of the first active pattern; aplurality of bit line structures on the first region of the substrate; afirst contact plug structure on the first active pattern and between twoadjacent bit line structures of the plurality of bit line structures; acapacitor on the first contact plug structure; a plurality of keystructures on the second region of the substrate, each of the pluralityof key structures having an upper surface substantially coplanar with anupper surface of each of the plurality of bit line structures; a trenchdisposed between two adjacent key structures of the plurality of keystructures that are spaced apart from each other; a filling pattern in alower portion of the trench, the filling pattern having a flat uppersurface and including a conductive material; and a first conductivestructure on the flat upper surface of the filling pattern, an uppersidewall of the trench, and the upper surface of each of the pluralityof key structures.
 12. The semiconductor device according to claim 11,wherein the first region of the substrate includes a cell region and aperipheral circuit region at least partially surrounding the firstregion, wherein the semiconductor device further comprises: a secondgate structure on the first active pattern on the peripheral circuitregion of the substrate; a second contact plug on the first activepattern adjacent to the second gate structure; and a wiring on thesecond contact plug, and wherein an upper surface of the wiring issubstantially coplanar with an upper surface of the first contact plugstructure.
 13. The semiconductor device according to claim 12, whereinthe wiring includes the same material as the first conductive structure.14. The semiconductor device according to claim 11, wherein each of theplurality of key structures and each of the plurality of bit linestructures have an insulation pattern, a second conductive structure, abarrier pattern, a metal pattern, and a capping pattern sequentiallystacked on the substrate.
 15. The semiconductor device according toclaim 11, wherein each of the plurality of key structures and each ofthe plurality of bit line structures extend in a first directionsubstantially parallel to the upper surface of the substrate, andwherein the plurality of key structures are spaced apart from each otherin a second direction substantially parallel to the upper surface of thesubstrate and crossing the first direction, and wherein the plurality ofbit line structures are spaced apart from each other in the seconddirection.
 16. The semiconductor device according to claim 15, wherein adistance in the first direction between two adjacent key structures ofthe plurality of key structures is greater than a distance in the firstdirection between two adjacent bit line structures of the plurality ofbit line structures.
 17. The semiconductor device according to claim 11,wherein the first contact plug structure includes a lower contact plugand an upper contact plug sequentially stacked on the first activepattern, and wherein the lower and upper contact plugs includesubstantially the same materials as those of the filling pattern and thefirst conductive structure, respectively.
 18. The semiconductor deviceaccording to claim 17, wherein the filling pattern includes dopedpolysilicon, and wherein the first conductive structure includes metal.19. The semiconductor device according to claim 17, further comprising:a first metal silicide pattern between the lower and upper contactplugs; and a second metal silicide pattern between the first and secondconductive structures, wherein the first and second metal silicidepatterns include substantially the same material.
 20. A semiconductordevice comprising: a substrate including: a chip region; and a scribelane region surrounding the chip region; a bit line structure on thechip region of the substrate; a first spacer structure on a sidewall ofthe bit line structure; a plurality of key structures on the scribe laneregion of the substrate, each of the plurality of key structures havingan upper surface substantially coplanar with an upper surface of the bitline structure; a second spacer structure on a sidewall of each of theplurality of key structures; a trench disposed between two adjacent keystructures of the plurality of key structures, wherein the two adjacentkey structures are spaced apart from each other in a first directionsubstantially parallel to an upper surface of the substrate; a fillingpattern in a lower portion of the trench, the filling pattern includinga first conductive material; and a conductive structure on an uppersurface of the filling pattern, an upper sidewall of the trench, and theupper surface of each of the plurality of key structures, the conductivestructure including a second conductive material.